Direct generation of Ti-enolate of α-CF3 ketone:: Theoretical study and high-yielding and diastereoselective aldol reaction
Direct generation of Ti-enolate of α-CF3 ketone:: Theoretical study and high-yielding and diastereoselective aldol reaction
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DOI：
10.1021/ja046518a
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发表时间：
2004-10-20
影响因子：
15
通讯作者：
Mikami, K
中科院分区：
文献类型：
--
作者：
Itoh, Y;Yamanaka, M;Mikami, K
报道了α-CF_3酮直接生成钛烯醇化物及其Aldol反应的成功。还报道了反应过程中Ti-F相互作用的重要性。
Success in the direct generation of the Ti-enolate of α-CF3ketone and its aldol reaction is reported. The importance of Ti−F interaction during the course of the reaction is also reported.