Mechanistic role of water in HSSZ-13 catalyzed methanol-to-olefins conversion

Mechanistic role of water in HSSZ-13 catalyzed methanol-to-olefins conversion
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DOI:
10.1039/c9cy01015g
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发表时间:
2019-08
影响因子:
5
通讯作者:
Praveen Bollini;Thomas T. Chen;M. Neurock;A. Bhan
Praveen Bollini;Thomas T. Chen;M. Neurock;A. Bhan
中科院分区:
化学2区
文献类型:
--
作者:
Praveen Bollini;Thomas T. Chen;M. Neurock;A. Bhan

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链引发和终止速率的衰减以及在甲醇至烯烃(MTO)转化中观察到的与水共进料的更高周转能力可能是由于甲醛水解。
Attenuation of chain initiation and termination rates and higher turnover capacities in methanol-to-olefins (MTO) conversion observed with water co-feeds are plausibly due to formaldehyde hydrolysis.