Roll coated large area ITO- and vacuum-free all organic solar cells from diketopyrrolopyrrole based non-fullerene acceptors with molecular geometry effects

Roll coated large area ITO- and vacuum-free all organic solar cells from diketopyrrolopyrrole based non-fullerene acceptors with molecular geometry effects
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由具有分子几何效应的二酮吡咯并吡咯基非富勒烯受体制成的辊涂大面积 ITO 和无真空全有机太阳能电池

DOI:
10.1039/c6ra06898g
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发表时间:
2016-04
期刊:
影响因子:
3.9
通讯作者:
Yu Donghong
Yu Donghong
中科院分区:
化学3区
文献类型:
--
作者:
Br;t Rasmus Guldbaek;Zhang Fei;Andersen Thomas Rieks;Angmo Dechan;Shi Minmin;Gurevich Leonid;Krebs Frederik C.;Andreasen Jens Wenzel;Yu Donghong

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In this paper, we investigate three diketopyrrolopyrrole (DPP) based small molecular non-fullerene acceptors, namely Ph(DPP)3, Ph(DPP)2, and PhDMe(DPP)2, focusing on molecular geometry effects on the frontier orbital level, light absorption, molecular configuration, electron mobility, thin film morphology, and photovoltaic performance of both spin-coated ITO based and roll coated large area, ITO- and vacuum-free organic solar cells (OSCs). For spin-coated devices based on P3HT as the donor polymer the solar cells gave power conversion efficiencies (PCEs) in the following order for (P3HT:PhDMe(DPP)2, 0.65%) > (P3HT:Ph(DPP)2, 0.48%) > (P3HT:Ph(DPP)3, 0.31%). All devices present an open circuit voltage (Voc) higher than 1.0 V. For the roll-coated devices, the PCEs were found to fall in another order and with lower values (P3HT:Ph(DPP)3, 0.54%) > (P3HT:Ph(DPP)2, 0.43%) > (P3HT:PhDMe(DPP)2, 0.04%) and the highest Voc was 0.82 V. Our preliminary results highlight the influence of geometry, structure and processing on the performance of non-fullerene acceptors.
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