Preparation and study of an f,f,f′,f" covalently linked tetranuclear hetero-trimetallic complex - a europium, terbium, dysprosium triad

Preparation and study of an f,f,f′,f" covalently linked tetranuclear hetero-trimetallic complex - a europium, terbium, dysprosium triad
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DOI:
10.1039/c2cc35931f
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发表时间:
2013-01-01
影响因子:
4.9
通讯作者:
Faulkner, Stephen
Faulkner, Stephen
中科院分区:
化学2区
文献类型:
--
作者:
Sorensen, Thomas Just;Tropiano, Manuel;Faulkner, Stephen

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通过Ugi反应将三个动力学稳定的配合物偶联在一起,合成了一个含有两个镝离子、一个铽离子和一个铕离子的异三金属四核镧系配合物。共价连接的三金属系统表现出从所有不同的镧系中心的发光。
A heterotrimetallic tetranuclear lanthanide complex containing two dysprosium ions, a terbium ion and a europium ion has been prepared by coupling three kinetically stable complexes together using the Ugi reaction. The covalently linked trimetallic system exhibits luminescence from all the different lanthanide centres.