Printing PEDOT from EDOT via plasma-assisted inkjet printing
Printing PEDOT from EDOT via plasma-assisted inkjet printing
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DOI：
10.1088/1361-6463/ab1ef2
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发表时间：
2019-05
期刊：
影响因子：
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通讯作者：
Kaishu Nitta;Masanao Tsumaki;Tomoya Kawano;K. Terashima;Tsuyohito Ito
中科院分区：
文献类型：
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作者：
Kaishu Nitta;Masanao Tsumaki;Tomoya Kawano;K. Terashima;Tsuyohito Ito
我们展示了通过等离子体辅助喷墨印刷的3，4-乙撑二氧噻吩（EDOT）单体原液油墨和印刷所得的聚（3，4-乙撑二氧噻吩）（PEDOT）的同时聚合。通过印刷线的拉曼和傅里叶变换红外（FT-IR）光谱证实了EDOT的等离子体诱导聚合。此外，我们还实现了等离子体诱导聚合PEDOT与聚（苯乙烯磺酸盐）（PSS）的导电膜的合成从EDOT。因此，我们在硼硅酸盐玻璃衬底上制备了电导率为10−2 Scm−1的PEDOT/PSS薄膜。我们的方法实现了（i）直接图案化与PEDOT聚合和（ii）掺杂与PEDOT聚合作为单独的过程，我们的结果表明，现场印刷导电PEDOT/PSS与聚合是可能的，通过使用喷墨系统，甚至耐强酸性的PSS。
We demonstrate the simultaneous polymerization of 3,4-ethylenedioxythiophene (EDOT) monomer stock solution ink and printing of the resulting poly(3,4-ethylenedioxythiophene) (PEDOT) via plasma-assisted inkjet printing. The plasma-induced polymerization of EDOT is confirmed via Raman and Fourier-transform infrared (FT-IR) spectroscopies of the printed line. Furthermore, we also achieve plasma-induced polymerization of PEDOT with poly(styrenesulfonate) (PSS) for the synthesis of an electrically conductive film from EDOT. Consequently, we fabricate a PEDOT/PSS film with conductivity of the order of 10−2 Scm−1 on a borosilicate glass substrate. Our approach achieves (i) direct patterning with PEDOT polymerization and (ii) doping with PEDOT polymerization as separate processes, and our results suggest that on-site printing of conductive PEDOT/PSS with polymerization is possible through the use of an inkjet system with resistance to even the strong acidity of PSS.