Glycosylation via remote activation of anomeric leaving groups: Development of 2-(2-propylsulfinyl)benzyl glycosides as novel glycosyl donors
Glycosylation via remote activation of anomeric leaving groups: Development of 2-(2-propylsulfinyl)benzyl glycosides as novel glycosyl donors
复制标题
通过远程激活异头离去基团进行糖基化：开发 2-(2-丙基亚磺酰基)苯甲基糖苷作为新型糖基供体
DOI：
10.1039/c5qo00359h
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发表时间：
2016
影响因子：
5.4
通讯作者：
Wan Q.
中科院分区：
文献类型：
--
作者：
Shu P.;Yao W.;Xiao X.;Sun J.;Zhao X.;Zhao Y.;Xu Y.;Tao J.;Yao G.;Zeng J.;Wan Q.
2-(2-丙基亚磺酰基)苯甲基糖苷被设计为一种新型糖基供体，可以通过远程模式激活。该糖基供体及其还原形式可以在潜在活性糖基化策略中分别充当活性供体和潜在供体。本文报道了这种新型糖基供体的发现细节。
2-(2-Propylsulfinyl)benzyl glycoside was designed as a new type of glycosyl donor which could be activated via remote mode. This glycosyl donor and its reduced form could act as active and latent donors respectively in a latent-active glycosylation strategy. Details of the discovery of this novel glycosyl donor are reported in this article.