The first general method for Z-selective olefination of acylsilanes via ynolate anions providing multisubstituted alkenes
The first general method for Z-selective olefination of acylsilanes via ynolate anions providing multisubstituted alkenes
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DOI：
10.1021/ja026275r
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发表时间：
2002-06-19
影响因子：
15
通讯作者：
Shishido, K
中科院分区：
文献类型：
--
作者：
Shindo, M;Matsumoto, K;Shishido, K
我们首次开发了酰基硅烷通过炔醇盐阴离子立体选择性烯化制备（Z）-β-硅烷基-α，β-不饱和酯的通用方法，并由此得到三取代和四取代烯烃。
We have developed the first general method for a stereoselective olefination of acylsilanes via ynolate anions to produce (Z)-β-silyl-α,β-unsaturated ester, which leads to tri- and tetrasubstituted alkenes.