EuS Nano-assembles Linked with Photo-functional Naphthalenedithiols

EuS Nano-assembles Linked with Photo-functional Naphthalenedithiols
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与光功能萘二硫醇连接的 EuS 纳米组装体

DOI:
10.1080/15421406.2013.805092
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发表时间:
2013
期刊:
Mol. Cryst. Liq. Cryst.
影响因子:
--
通讯作者:
Y. Hasegawa
Y. Hasegawa
中科院分区:
--
文献类型:
--
作者:
○Taro Hamasaki;Yuka Aoyama;Junichi Kawasaki;Fumitoshi Kakiuchi;Takuya Kochi;○濵﨑太郎・垣内史敏・河内卓彌;Y. Hasegawa;Y. Hasegawa;Y. Hasegawa;Y. Hasegawa;Y. Hasegawa;Y. Hasegawa

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报道了一种新型的光功能的萘二硫醇(NpDDT)作为连接分子形成EUS纳米晶组装(EUS纳米组装)。以1,4-二羟基萘和1,10-十一烷二硫醇为原料,在80℃下反应1小时合成了NpDDT,并通过透射电子显微镜观察到NpDDT与EUS形成了纳米组装。利用发射光谱和发射量子产额表征了EUS与NpDDT纳米组装的光物理性质。NpDDT中萘单元的发射量子产率取决于EUS纳米组装的聚集尺寸。首次报道了新型发光材料NpDDT作为一种有效的连接材料用于半导体EUS纳米组装的形成和观察。
Novel photo-functional naphthalenedithiol (NpDDT) as a linker molecule for formation of EuS nanocrystal assembles (EuS nano-assembles) has been reported. NpDDT is synthesized by the reaction of 1,4-dihydroxynaphthalene with 1,10-decanedithiol in benzene at 80°C for 1 hour.Formation of EuS nano-assembles with NpDDT is observed by TEM measurement. Photophysical properties of EuS nano-assembles with NpDDT are characterized using the emission spectra and the emission quantum yields. The emission quantum yields of naphthalene units in NpDDT are depended on the aggregation size of EuS nano-assembles. Novel luminescent NpDDT has been reported as an effective linker material for formation and observation of semiconductor EuS nano-assembles for the first time.
溶液中具有磁光特性的立方体 EuS 纳米晶体的尺寸控制聚集
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