The Synthesis of a 2-Deoxy-2-Acetonyl Sugar from its Corresponding Natural Saccharide

The Synthesis of a 2-Deoxy-2-Acetonyl Sugar from its Corresponding Natural Saccharide
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DOI:
10.3184/174751912x13326765667344
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发表时间:
2012-04
影响因子:
1.4
通讯作者:
Ying Zhang;Yang Liu;Zhijun Wang;Zhongfu Wang;Linjuan Huang
Ying Zhang;Yang Liu;Zhijun Wang;Zhongfu Wang;Linjuan Huang
中科院分区:
化学4区
文献类型:
--
作者:
Ying Zhang;Yang Liu;Zhijun Wang;Zhongfu Wang;Linjuan Huang

文献摘要

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报道了以天然糖为原料,通过2-碘化糖的甲基化反应合成2-脱氧-2-丙酮基糖的方法。简化的反应过程不需要在严格控制的条件下进行,为在普通实验室条件下合成2-脱氧-2-丙酮糖提供了一条有效的途径。
An efficient synthesis of a 2-deoxy-2-acetonyl sugar from its corresponding natural sugar by methallylation of the 2–iodo sugar is reported. The simplified procedure eliminated the need to carry out the reaction under strictly controlled conditions, giving an efficient route for the synthesis of 2-deoxy-2-acetonyl sugar under ordinary laboratory conditions.