Efficient Catalytic Hydrolysis of Disaccharides by Cerium(IV) Ion at pH 7

Efficient Catalytic Hydrolysis of Disaccharides by Cerium(IV) Ion at pH 7
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pH 7 条件下铈 (IV) 离子对二糖的高效催化水解

DOI:
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发表时间:
1997
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影响因子:
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通讯作者:
K. Seri
K. Seri
中科院分区:
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文献类型:
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作者:
H. Ishida;K. Seri

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CeIV(NH4)2(NO3)6在pH7.0下有效地催化各种二糖如蔗糖、麦芽糖、乳糖和纤维二糖的水解,蔗糖水解的活化能为14.4 kcal mol−1,显著小于0.18 N HCl的活化能30 kcal mol−1。
CeIV(NH4)2(NO3)6 effectively catalyses hydrolysis of various disaccharides such as sucrose, maltose, lactose, and cellobiose at pH 7.0, and activation energy for sucrose hydrolysis was found to be 14.4 kcal mol−1, which is remarkably smaller than that by 0.18 N HCl, 30 kcal mol−1.