Behaviour of Environmental Plutonium at very Low Concentration
Behaviour of Environmental Plutonium at very Low Concentration
复制标题
环境钚在极低浓度下的行为
DOI：
10.1524/ract.1992.5859.1.53
复制
发表时间：
1992
期刊：
影响因子：
--
通讯作者：
J. Adloff
中科院分区：
文献类型：
--
作者：
R. Guillaumont;J. Adloff
钚以极低的浓度广泛分布于环境系统中，并能发生络合和反硝化反应。在这些浓度水平下，质量作用定律描述反应平衡状态的有效性可能受到质疑。具体的情况下，如络合的钚，和Pu（V）在减法规模的反式进行了讨论。推测完成的反应，涉及不到100个钚原子的发展。
Plutonium is widely distributed in environmental systems at very low concentrations and can undergo complexation and disproportionation reactions. At these concentration levels, the validity of the law of mass action for describing the equilibrium state of the reactions may be questioned. Specific cases, such as complexation of Pu, and disproportionation of Pu(V) at the subtracer scale are discussed. Speculations about the completion of reactions involving less than 100 Pu atoms are developed.