Synthesis of Liquid-Crystalline, Highly Luminescent π-Conjugated 1,3,5-Triazine Derivatives by Palladium-Catalyzed Cross-Coupling Reaction

Synthesis of Liquid-Crystalline, Highly Luminescent π-Conjugated 1,3,5-Triazine Derivatives by Palladium-Catalyzed Cross-Coupling Reaction
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钯催化交叉偶联反应合成液晶高发光 π-共轭 1,3,5-三嗪衍生物

DOI:
10.1080/713738587
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发表时间:
2002
期刊:
影响因子:
--
通讯作者:
Takakazu Yamamoto
Takakazu Yamamoto
中科院分区:
--
文献类型:
--
作者:
Chi;Takakazu Yamamoto

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采用Pd(0)/Cu(I)催化的碳-碳偶联反应合成了一类具有长烷氧基侧链的2,4,6-三苯基-1,3,5-三嗪衍生物。这些化合物表现为液晶材料,在光致发光中显示出高于70%的量子产率。
A new class of 2,4,6-triphenyl-1,3,5-triazine derivatives having long alkoxyl side chains have been synthesized by a Pd(0)/Cu(I)-catalyzed carbon-carbon coupling reaction. These compounds behave as liquid-crystalline materials and show quantum yields higher than 70% in photoluminescence.