Palladium-catalyzed three-component reaction of ferrocenyl allenes, aryl iodides and active methylene compounds: regio- and stereoselective synthesis of (E)-alkenylferrocenes

Palladium-catalyzed three-component reaction of ferrocenyl allenes, aryl iodides and active methylene compounds: regio- and stereoselective synthesis of (E)-alkenylferrocenes
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DOI:
10.1039/c3ra43738h
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发表时间:
2013-10
期刊:
影响因子:
3.9
通讯作者:
Shufeng Chen;Zhenlong Gao;Chao Wu;Haiying Zhao;Baoguo Li
Shufeng Chen;Zhenlong Gao;Chao Wu;Haiying Zhao;Baoguo Li
中科院分区:
化学3区
文献类型:
--
作者:
Shufeng Chen;Zhenlong Gao;Chao Wu;Haiying Zhao;Baoguo Li

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A concise protocol for the synthesis of (E)-alkenylferrocene derivatives based on the palladium-catalyzed three-component reaction of ferrocenyl allenes, aryl iodides and active methylene compounds was developed. This transformation exemplifies a simple method for the efficient synthesis of various mono- or bisallyl-substituted alkenylferrocenes in good yields with excellent regio- and stereoselectivities.