Comparative survey of levels of chlorinated cyclodiene pesticides in breast milk from some cities of China, Korea and Japan
Comparative survey of levels of chlorinated cyclodiene pesticides in breast milk from some cities of China, Korea and Japan
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DOI：
10.1016/j.chemosphere.2012.05.098
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发表时间：
2012-10-01
期刊：
影响因子：
8.8
通讯作者：
Haraguchi, Koichi
中科院分区：
文献类型：
--
作者：
Fujii, Yukiko;Ito, Yoshiko;Haraguchi, Koichi
通过测量来自中国210人的70份母乳样本中20种有机氯农药的水平，评估了母亲接触有机氯农药（OCPs）的情况。韩国和日本。采用气相色谱/质谱法（GC/MS）对ocp进行电子捕获负电离（ECNI）监测。结果显示，中国的-六氯环己烷和六氯苯含量比其他国家高一个数量级，而日本的氯丹和多氯联苯含量最高。在大多数样品中检测到环氧七氯、狄氏剂、内啡肽、毒杀芬和灭螨，这些化学物质的含量在日本显著较高（0.8-4.5 ng g（-1）脂），其次是韩国（0.2-4.7 ng g（-1）脂），中国最低（低于1.0 ng g（-1）脂）。在所有分析的样品中检测到的α -和β -硫丹的脂质水平范围为0.9-1.5 ng g(-1)，韩国样品中的α -和β -硫丹含量高于中国样品。(C) 2012 Elsevier Ltd.版权所有。
Exposure of mothers to organochlorine pesticides (OCPs) was assessed by measuring the levels of 20 OCPs in 70 human breast milk samples pooled from 210 individuals from China. Korea and Japan. The OCPs were analyzed using gas chromatography/mass spectrometry (GC/MS) in electron capture negative ionization (ECNI) monitoring. The results showed that beta-hexachlorocyclohexane and hexachlorobenzene were one order of magnitude higher in China than in the other nations, whereas chlordanes and polychlorinated biphenyl levels were highest in Japan. Heptachlor epoxide, dieldrin, endrin, toxaphenes and mirex were detected in most samples, and levels of these chemicals were significantly higher in Japan (0.8-4.5 ng g(-1) lipid), followed by Korea (0.2-4.7 ng g(-1) lipid), and lowest in China (less than 1.0 ng g(-1) lipid). alpha- and beta-endosulfans were detected at a range of 0.9-1.5 ng g(-1) lipid levels in all samples analyzed, and their levels were higher in Korean than in Chinese samples. (C) 2012 Elsevier Ltd. All rights reserved.