Au(i)-Catalyzed expeditious access to naphtho[2,3-c]furan-1(3-H)-ones from readily available propargylic ynoates

Au(i)-Catalyzed expeditious access to naphtho[2,3-c]furan-1(3-H)-ones from readily available propargylic ynoates
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Au(i) 催化从容易获得的炔丙酸酯快速生成萘并[2,3-c]呋喃-1(3-H)-酮

DOI:
10.1039/c8cc06056h
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发表时间:
2018
影响因子:
4.9
通讯作者:
Zhang Liming
Zhang Liming
中科院分区:
化学2区
文献类型:
--
作者:
Li Ting;Wang Huiyan;Qian Pengcheng;Yang Yuhan;Li Bo;Zhang Liming

文献摘要

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Gold(I)-catalyzed facile construction of naphtho[2,3-c]furan-1(3-H)-ones from readily available propargylic ynoates has been developed. This reaction tolerates a range of substituents, exhibits a moderate to good efficiency, and reveals a new reaction pathway of an in situ-generated carboxyallene intermediate in gold catalysis.