Rh-catalyzed synthesis of helically chiral and ladder-type molecules via [2 + 2 + 2] and formal [2 + 1 + 2 + 1] cycloadditions involving C-C triple bond cleavage.
Rh-catalyzed synthesis of helically chiral and ladder-type molecules via [2 + 2 + 2] and formal [2 + 1 + 2 + 1] cycloadditions involving C-C triple bond cleavage.
复制标题
DOI：
10.1021/ja074914y
复制
发表时间：
2007-09
影响因子：
15
通讯作者：
Ken Tanaka;A. Kamisawa;T. Suda;K. Noguchi;M. Hirano
中科院分区：
文献类型：
--
作者：
Ken Tanaka;A. Kamisawa;T. Suda;K. Noguchi;M. Hirano
我们已经开发了通过Rh催化的[2 + 2 + 2]环加成高度对映选择性合成官能化的螺旋手性分子和通过前所未有的Rh催化的涉及C-C三键断裂的正式[2 + 1 + 2 + 1]环加成合成梯形分子。
We have developed highly enantioselective synthesis of functionalized helically chiral molecules via a Rh-catalyzed [2 + 2 + 2] cycloaddition and synthesis of ladder-type molecules via an unprecedented Rh-catalyzed formal [2 + 1 + 2 + 1] cycloaddition involving C−C triple bond cleavage.