Mg-C 系合金の創製とその水素親和性

Mg-C 系合金の創製とその水素親和性
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Mg-C合金的制备及其氢亲和力

DOI:
10.2320/jinstmet.72.780
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发表时间:
2008
影响因子:
--
通讯作者:
俊郎 久慈
俊郎 久慈
中科院分区:
材料科学4区
文献类型:
--
作者:
貴充 本城;関 信木;俊郎 久慈

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镁基合金具有重量轻、吸氢能力强等优点,因此在近几十年来得到了广泛的研究。石墨作为氢吸收剂近来也受到极大关注。本文采用球磨法制备了Mg-C合金,并对其加氢性能进行了研究。首先将粉末与1:1摩尔比的Mg与石墨混合。研磨球和罐由SUS 304制成。该工序在Ar气体气氛下,用振动球磨机以11.8Hz的速度进行60小时。将制备的粉末在填充有Ar气体的手套箱中处理。球磨后,样品显示出新的X射线衍射峰,其不是来自Mg和/或石墨的峰。在453 K和1.8 MPa氢气压力下证实了粉末与氢气的亲和力。从热脱附光谱(TDS)谱估计吸收的氢的总量为2.0重量%。
Magnesium based alloys possess light-weight and high hydrogen absorption capacity so that they have been investigated extensively for several decades. Great attention also has recently been paid to graphite as a hydrogen absorber. In this study Mg-C alloys were prepared by ball milling and their hydrogenation properties were investigated. Powders were first mixed with a 1 : 1 molar ratio of Mg to graphite. Milling balls and a pot were made of SUS304. This process was performed with a vibration ball mill at the speed of 11.8 Hz under an Ar gas atmosphere for 60 hours. The prepared powders were handled in a glove box filled with an Ar gas. After ball milling, samples showed a new X-ray diffraction peak, which was either not a peak from Mg and/or graphite. An affinity for the powders with hydrogen was confirmed at 453 K and the 1.8 MPa hydrogen pressure. The total amount of absorbed hydrogen was estimated to be 2.0 wt% from the thermal desorption spectroscopy (TDS) spectrum.
用于多轴应力测量的金属基压电复合材料的创建
DOI: --
发表时间: 2022
期刊:
影响因子: --
作者:
Takumi Ohara;Ke-Hsuan Wang;Yoshiro Imura;Takeshi Kawai;山下泰優,柳迫徹郎
通讯作者: 山下泰優,柳迫徹郎