Toughening and stabilizing MOF crystals via polymeric guest inclusion
Toughening and stabilizing MOF crystals via polymeric guest inclusion
复制标题
通过聚合物客体夹杂物增韧和稳定 MOF 晶体
DOI：
10.1039/d2dt01425d
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发表时间：
2022
影响因子：
4
通讯作者：
Takashi Uemura
中科院分区：
文献类型：
--
作者：
Tomoya Iizuka;Nobuhiko Hosono;Takashi Uemura
由于金属有机骨架材料的实际应用，提高其机械性能和稳定性是一个重要的研究课题。在此，我们通过用聚合物链填充MOF孔来调节MOF的机械性能。机械性能反映了聚合物客体的填充率、分子量和固有柔性，赋予M0F改善的抗机械压力的弹性和韧性。
Improving the mechanical properties and stability of metal–organic frameworks (MOFs) is of significant interest due to their practical applications. Herein, we tune the mechanical properties of MOFs by filling the MOF pores with polymer chains. The mechanical properties reflect the filling rate, molecular weight, and inherent flexibility of the polymeric guests, imparting MOFs with improved resilience and toughness against mechanical pressures.