A self-confinement synthesis of a POM-decorated MOF thin film for actively hydrolyzing ethyl acetate
A self-confinement synthesis of a POM-decorated MOF thin film for actively hydrolyzing ethyl acetate
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自限制合成 POM 修饰的 MOF 薄膜用于主动水解乙酸乙酯
DOI：
10.1039/d0cc05637e
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发表时间：
2020
影响因子：
4.9
通讯作者：
Peng Xinsheng
中科院分区：
文献类型：
--
作者：
Fang Zhou;Chen Danke;Li Zhuoyi;Ma Xu;Wan Xinyi;Deng Zheng;Peng Xinsheng
以金属氢氧化物纳米链和聚氧乙烯酸盐（POMs）为原料，采用自限制法在室温下制备了POM@MOFs薄膜，该薄膜对乙酸乙酯具有较高的水解活性（1027.5 μmol g−1 min−1），且稳定性好，易于回收.这提供了容易地制备纳米POM@MOF薄膜催化剂的一般方法。
Hybrid heterogeneous solid acid catalysts polyoxometalate-decorated metal organic framework (POM@MOFs) thin films were synthesized from POMs and metal hydroxide nanostrands via a self-confinement method at room temperature, which show high hydrolyzing activity (1027.5 μmol g−1 min−1) for ethyl acetate with durable stability and an easy recovery. This provides a general way to easily prepare nano POM@MOF thin film catalysts.