Addition of diethyl bromodifluoromethylphosphonate to various alkenes initiated by Co(III)/Zn bimetal redox system

Addition of diethyl bromodifluoromethylphosphonate to various alkenes initiated by Co(III)/Zn bimetal redox system
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DOI:
10.1039/p19930000327
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发表时间:
1993
期刊:
Journal of The Chemical Society-perkin Transactions 1
影响因子:
--
通讯作者:
Changming Hu;Jian Chen
Changming Hu;Jian Chen
中科院分区:
其他
文献类型:
--
作者:
Changming Hu;Jian Chen

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The addition of diethyl bromodifluoromethylphosphonate 1 to various alkenes 2 initiated by cobaloxime(III)/Zn bimetal redox system gives 1:1 Michael-type adducts 3 in moderate to good yields. A radical mechanism is proposed.