An NMR study of the equilibration of D-glucaric acid with lactone forms in aqueous acid solutions

An NMR study of the equilibration of D-glucaric acid with lactone forms in aqueous acid solutions
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DOI:
10.1080/07328300701787172
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发表时间:
2007-09-01
影响因子:
1
通讯作者:
Kiely, Donald E.
Kiely, Donald E.
中科院分区:
化学4区
文献类型:
--
作者:
Brown, Jolene M.;Manley-Harris, Merilyn;Kiely, Donald E.

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通过 NMR 研究了在有或没有酸催化的情况下 D-葡萄糖二酸及其内酯形式的水溶液平衡。模拟了接近平衡的动力学,并获得了近似平衡和速率常数。
The aqueous solution equilibration of D-glucaric acid with its lactone forms was studied by NMR with and without acid catalysis. The kinetics of the approach to equilibrium were simulated, and approximate equilibrium and rate constants were obtained.