S 1 Electronic Supplementary Information Solvent Exchange in Preformed Photocatalyst-Donor Pre-cursor Complex Determines Efficiency
S 1 Electronic Supplementary Information Solvent Exchange in Preformed Photocatalyst-Donor Pre-cursor Complex Determines Efficiency
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S 1 电子补充信息 预制光催化剂-供体前体复合物中的溶剂交换决定效率
DOI：
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发表时间：
2017
期刊：
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通讯作者：
K. Kubarych
中科院分区：
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作者：
Laura M. Kiefer;K. Kubarych
为了补充我们的2DIR结果，我们进行了ET(30)实验，通过将TEOA/溶剂与甜菜碱-30或莱克哈特染料、(2，6-diphenyl-4-(2，4，6-triphenyl-1pyridinio)phenolate)，的比例结合起来，并收集了每个混合物的UV-Vis光谱。甜菜碱-30在以前的优先溶剂化研究中已被使用，并在这里被用来表征三乙醇胺在本研究中使用的溶剂二甲基亚砜-30中的优先溶剂化。
To complement our 2DIR results, we performed ET(30) experiments by combining ratios of TEOA/Solvent with betaine-30, or Reichardt’s Dye, (2,6-diphenyl-4-(2,4,6-triphenyl-1pyridinio)phenolate), and collected UV-Vis spectra of each mixture. Betaine-30 has been used in previous preferential solvation studies, and was used here to characterize preferential solvation of triethanolamine in the solvents used in this study, dimethyl sulfox-