Room temperature oxidation of alcohols with 1 atm dioxygen and air catalyzed by a novel three-dimensional microporous ruthenium(II,III) 4,4′4",4′"(21H,23H-porphine-5,10,15,20-tetrayl) tetrakisbenzoate tetrafluoroborate
Room temperature oxidation of alcohols with 1 atm dioxygen and air catalyzed by a novel three-dimensional microporous ruthenium(II,III) 4,4′4",4′"(21H,23H-porphine-5,10,15,20-tetrayl) tetrakisbenzoate tetrafluoroborate
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DOI：
10.1016/j.catcom.2006.02.011
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发表时间：
2006-09-01
影响因子：
3.7
通讯作者：
Mori, Wasuke
中科院分区：
文献类型：
--
作者：
Kato, Chika Nozaki;Ono, Masato;Mori, Wasuke
合成了一种新型三维微孔钌(II,III)聚合物配合物[Ru-2(II,III)(H2TCPP)]BF4 (1) (H2TCPP = 4,4',4',4'"-(21H,23H-卟啉-5,10,15,20-四基)四基苯甲酸)，并通过元素分析、热重/差热分析、磁性分析等手段对其进行了表征。磁化率、FT-IR、漫反射紫外-可见光、ESR、X 射线粉末衍射、BET 分析以及氮和氧吸附测量，配合物 1 在室温下对各种类型的醇（特别是脂肪伯醇）与分子氧和空气的多相氧化表现出有效的催化性能（c）2006 Elsevier B.V. 保留所有权利。
A novel three-dimensional microporous ruthenium (II,III) polymer complex, [Ru-2(II,III)(H2TCPP)]BF4 (1) (H2TCPP = 4,4',4',4'"- (21H,23H-porphine-5,10,15,20-tetrayl)tetrakis benzoic acid) was synthesized and characterized by elemental analysis, TG/DTA, magnetic susceptibility, FT-IR, diffuse reflectance UV-Vis, ESR, X-ray powder diffraction, BET analysis, and nitrogen and oxygen adsorption measurements. Complex 1 exhibited an effective catalytic performance for the heterogeneous oxidation of various types of alcohols, particularly primary aliphatic alcohols, with molecular oxygen and air without any additives at room temperature. (c) 2006 Elsevier B.V. All rights reserved.