ANODIC OXIDATION STUDIES OF N,N-DIMETHYLANILINE .1. VOLTAMMETRIC AND SPECTROSCOPIC INVESTIGATIONS AT PLATINUM ELECTRODES
ANODIC OXIDATION STUDIES OF N,N-DIMETHYLANILINE .1. VOLTAMMETRIC AND SPECTROSCOPIC INVESTIGATIONS AT PLATINUM ELECTRODES
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DOI：
10.1021/ja00870a009
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发表时间：
1962-01-01
影响因子：
15
通讯作者：
ADAMS, RN
中科院分区：
文献类型：
--
作者：
MIZOQUCHI, T;ADAMS, RN
用常规伏安法、循环伏安法、塔菲尔图、原位分光光度法和电子顺磁共振技术研究了N，N-二甲基苯胺在铂电极上的阳极氧化过程。氧化反应主要生成N，N，N ′，N ′-四甲基联苯胺及其氧化醌类化合物。提出了氧化反应的一般机理。
The anodic oxidation of N, N-dimethylaniline at a platinum electrode in acidic buffers was examined by conventional and cyclic voltammetry, Tafel plot measurements, in situ spectrophotometric and electron paramagnetic resonance techniques. The oxidation was shown to lead to the formation of N, N, N', N'-tetramethylbenzidine and its oxidized quinoid as principal products. A general mechanismscheme forthe oxidation is presented.