Critical temperature of the LIESST effect in a series of hydrated and anhydrous complex salts [Fe(bpp)2]X2
Critical temperature of the LIESST effect in a series of hydrated and anhydrous complex salts [Fe(bpp)2]X2
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DOI：
10.1016/s0009-2614(02)00590-0
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发表时间：
2002-05-24
影响因子：
2.8
通讯作者：
Létard, JF
中科院分区：
文献类型：
--
作者：
Marcén, S;Lecren, L;Létard, JF
研究了一系列由2，6-二（吡唑-3-基）吡啶（bpp）配体衍生的水合和脱水自旋交叉化合物的磁性，并在10 K下研究了光诱导交叉.通过测定T（LIESST）来估计化合物保留光诱导HS信息的能力。分析了各化合物在T（LIESST）-T（1/2）图中的位置，讨论了盐的性质、水化程度和协同性对它们的影响。(C)出版社：Elsevier Science B. V.
The magnetic properties of a series of hydrated and dehydrated spin crossover compounds derived from the 2,6-bis(pyrazol-3-yl)pyridine (bpp) ligand have been reinvestigated and the light-induced crossover studied at 10 K. The capacity of a compound to retain the light-induced HS information has been estimated through the determination of the T(LIESST). The position of each compound in the T(LIESST)-T(1/2) diagram has been analyzed and the effect of the nature of the salt, hydration degree and cooperativity have been discussed. (C) 2002 Published by Elsevier Science B.V.