RAFT-functional ionic liquids: towards understanding controlled free radical polymerisation in ionic liquids
RAFT-functional ionic liquids: towards understanding controlled free radical polymerisation in ionic liquids
复制标题
RAFT 功能离子液体：了解离子液体中的受控自由基聚合
DOI：
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发表时间：
2009
期刊：
影响因子：
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通讯作者：
K. Thurecht
中科院分区：
文献类型：
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作者：
S. Puttick;D. Irvine;P. Licence;K. Thurecht
在不同的室温离子液体(RTIL)中进行了RAFT可控聚合甲基丙烯酸甲酯，以考察阴离子对繁殖速度和分子量控制的影响；通过“点击”型化学作为相容剂，制备了一种新型的RAFT-栓系离子液体，从而克服了用游离RAFT试剂观察到的分配效应，从而在如此广泛的RTIL范围内实现了前所未有的高水平控制。
RAFT controlled polymerisation of methyl methacrylate in various room temperature ionic liquids (RTILs) was carried out to investigate the effect of the anion on both propagation rate and control of molecular weight; a novel RAFT-tethered ionic liquid was prepared by “click” type chemistry to act as a compatibiliser thereby overcoming partitioning effects that were observed with the free RAFT agent and resulted in high levels of control never before achieved using RAFT in such a broad range of RTILs.
影响因子：
16.6
作者：
Rostovtsev, VV;Green, LG;Sharpless, KB
通讯作者：
Sharpless, KB