Electron-transfer kinetics of nitroxide radicals as an electrode-active material
Electron-transfer kinetics of nitroxide radicals as an electrode-active material
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DOI：
10.1246/bcsj.77.2203
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发表时间：
2004-12-01
影响因子：
4
通讯作者：
Nishide, H
中科院分区：
文献类型：
--
作者：
Suga, T;Pu, YJ;Nishide, H
用电化学方法研究了氮氧自由基衍生物4-（N-叔丁基-N-酰氨基）-叔丁基苯、4-（N-叔丁基-N-酰氨基）-甲氧基苯和2，2，6，6-四甲基哌啶基-N-氧自由基的电子转移速率常数，结果表明，这些自由基具有快速的电子转移过程，可作为高功率比电极活性材料.
The electron-transfer rate constants of nitroxide derivatives, 4-(N-t-butyl-N-oxylamino)-t-butylbenzene, 4-(N-t-butyl-N-oxylamino)methoxybenzene, and 2,2,6,6-tetramethylpiperidinyl-N-oxyl, were investigated by electrochemical methods, which demonstrated that these radicals can potentially be used as a high power-rate electrode-active material due to their fast electron-transfer process.