Ultrafast electronic spectroscopy for chemical analysis near liquid water interfaces: concepts and applications
Ultrafast electronic spectroscopy for chemical analysis near liquid water interfaces: concepts and applications
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用于液态水界面附近化学分析的超快电子光谱：概念和应用
DOI：
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发表时间：
2009
期刊：
影响因子：
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通讯作者：
B. Abel
中科院分区：
文献类型：
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作者：
O. Link;E. Lugovoy;K. Siefermann;Y. Liu;M. Faubel;B. Abel
化学分析电子能谱（ESCA）在概念上是一种光电子能谱，是一种化学特异性探针，主要用于表面分析。真空液体微射流技术的发展使挥发性液体在高蒸气压下的液相界面光电子发射测量成为可能。最近，我们利用高次软x射线和紫外/近红外飞秒脉冲结合真空中的液态水微束，在液体界面ESCA技术中加入了时间维度。概述了概念和技术细节，并强调了几个典型的应用。
Electron spectroscopy for chemical analysis (ESCA) being conceptually a photoelectron spectroscopy is established as a chemically specific probe mostly for surface analysis. Liquid phase ESCA for volatile liquids has become possible through the development of the liquid microjet technique in vacuum enabling the measurement of liquid interface photoelectron emission at the high vapor pressure of volatile liquids. Recently we have been able to add the dimension of time to the liquid interface ESCA technique employing high-harmonics soft X-ray and UV/near IR femtosecond pulses in combination with liquid water micro beams in vacuum. The concepts as well as technical details are outlined and several characteristic applications are highlighted.
影响因子：
35
作者：
Centurion, Martin;Reckenthaeler, Peter;Fill, Ernst E.
通讯作者：
Fill, Ernst E.
影响因子：
64.8
作者：
Cavalieri, A. L.;Mueller, N.;Heinzmann, U.
通讯作者：
Heinzmann, U.