Reversible Diels-Alder Chemistry as a Modular Polymeric Color Switch
Reversible Diels-Alder Chemistry as a Modular Polymeric Color Switch
复制标题
DOI：
10.1002/adma.201000361
复制
发表时间：
2010-07-06
影响因子：
29.4
通讯作者：
Barner-Kowollik, Christopher
中科院分区：
文献类型：
--
作者：
Pauloehrl, Thomas;Inglis, Andrew J.;Barner-Kowollik, Christopher
描述了一种基于可逆Diels-Alder化学的环戊二烯封端聚合物和高电子缺陷二硫代酯之间的完全可逆的聚合物颜色切换体系。详细的反应进程可以在分子水平上绘制出几个完整的开关周期，并得到ESI-MS研究的支持。
A fully reversible polymeric color-switch system based on reversible Diels-Alder chemistry between cyclopentadienyl capped polymers and highly electron deficient dithioesters is described. The detailed reaction progress could be mapped on a molecular level for several complete switching cycles and was underpinned by an ESI-MS study.