Synthesis of Regioselectively Functionalized Pyrenes via Transition-Metal-Catalyzed Electrocyclization
Synthesis of Regioselectively Functionalized Pyrenes via Transition-Metal-Catalyzed Electrocyclization
复制标题
通过过渡金属催化电环化合成区域选择性功能化芘
DOI：
10.1055/s-0030-1258238
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发表时间：
2010
期刊：
影响因子：
--
通讯作者：
Davis A
中科院分区：
文献类型：
--
作者：
Davis A
Transition-metal-catalyzed electrocyclic rearrangement of 2, 6-diethynyl-1, 1′-biphenyl precursors to form polysubstituted pyrenes is described. This method is useful for the preparation of pyrenes with uncommon substitution patterns, and selective integration of functional groups at the 1-, 2-, 3-, 5-, 7-and 9-positions is demonstrated.
