Aryne multifunctionalization with benzdiyne and benztriyne equivalents
Aryne multifunctionalization with benzdiyne and benztriyne equivalents
复制标题
用苯二炔和苯三炔等价物进行芳炔多官能化
DOI：
10.1039/c6cs00694a
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发表时间：
2017
影响因子：
46.2
通讯作者：
Yang Li
中科院分区：
文献类型：
--
作者：
Jiarong Shi;Yuanyuan Li;Yang Li
芳炔化学与其他合成方法相比最显著的特征之一是它能够同时用不同的取代基组合官能化苯环的邻位两个位置。此外，其余四个位置的官能化也可以通过多芳炔等价物来实现，其中在同一苯环的不同位置上产生多于一个三键。本教程综述总结了苯并二炔和苯并三炔等价物的应用，从合成有机化学的角度，以及在多环芳香族功能框架的制备。
One of the most distinct characters of aryne chemistry over other synthetic methodologies is its ability to simultaneously functionalize the vicinal two positions of a benzene ring with diverse combinations of substituents. Moreover, the functionalization of the remaining four positions can be also achieved through multiaryne equivalents, in which more than one triple bond is generated on the different locations of the same benzene ring. This tutorial review summarizes the applications of benzdiyne and benztriyne equivalents from the standpoint of synthetic organic chemistry as well as in the preparation of polycyclic aromatic functional frameworks.