CHIRAL LEWIS-ACIDS DERIVED FROM 1,8-NAPHTHALENEDIYLBIS(DICHLOROBORANE) - MECHANISTIC ASPECTS
CHIRAL LEWIS-ACIDS DERIVED FROM 1,8-NAPHTHALENEDIYLBIS(DICHLOROBORANE) - MECHANISTIC ASPECTS
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DOI：
10.1016/0040-4039(94)02227-3
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发表时间：
1995-01-09
影响因子：
1.8
通讯作者：
OH, T
中科院分区：
文献类型：
--
作者：
REILLY, M;OH, T
1，8-萘二基双（二氯硼烷）衍生的手性刘易斯酸是一种新型的双齿刘易斯酸，被发现是不对称Diels-Alder反应的催化剂。利用衍生自氨基酸的手性配体，已经用环戊二烯和各种α，β-不饱和醛实现了一系列对映选择性。这种新型的不对称双齿催化剂的一些机制方面已经解决。
Chiral Lewis acids derived from 1,8-Naphthalenediylbis(dichloroborane), a novel bidentate Lewis acid, have been found to be active catalysts for the asymmetric Diels-Alder reaction. Utilizing chiral ligands derived from amino acids, a range of enantioselectivities have been achieved with cyclopentadiene and various alpha,beta-unsaturated aldehydes. Some mechanistic aspects of this novel asymmetric bidentate catalyst have been addressed.