Modification of conjugated microporous poly-benzothiadiazole for photosensitized singlet oxygen generation in water
Modification of conjugated microporous poly-benzothiadiazole for photosensitized singlet oxygen generation in water
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DOI：
10.1039/c3cc38956a
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发表时间：
2013-01-01
影响因子：
4.9
通讯作者：
Vilela, Filipe
中科院分区：
文献类型：
--
作者：
Urakami, Hiromitsu;Zhang, Kai;Vilela, Filipe
采用硫醇-炔化学法合成了水分散性含炔共轭微孔聚苯并噻二唑，以提高其水溶性。以水溶性聚合物网络为非均相光催化剂，制备了单重态氧，并将其用于糠酸合成5-羟基-2（5 H）-呋喃酮的反应。
Water-dispersible alkyne-bearing conjugated microporous polybenzothiadiazoles were synthesized using thiol-yne chemistry to enhance water compatibility. The water compatible polymer networks were used as heterogeneous photocatalysts to generate singlet oxygen for the conversion of furoic acid to 5-hydroxy-2(5H)-furanone.