Core-branched CoSe2/Ni0.85Se nanotube arrays on Ni foam with remarkable electrochemical performance for hybrid supercapacitors
Core-branched CoSe2/Ni0.85Se nanotube arrays on Ni foam with remarkable electrochemical performance for hybrid supercapacitors
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泡沫镍上的核心支化 CoSe2/Ni0.85Se 纳米管阵列具有卓越的混合超级电容器电化学性能
DOI:
10.1039/c8ta08263d
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发表时间:
2018-10
影响因子:
11.9
通讯作者:
Feng Jicai
中科院分区:
文献类型:
--
作者:
Lin Jinghuang;Wang Haohan;Yan Yaotian;Zheng Xiaohang;Jia Henan;Qi Junlei;Cao Jian;Tu Jinchun;Fei Weidong;Feng Jicai
Nanotube arrays have shown great potential in a variety of important applications, such as hybrid supercapacitors. In order to endow nanotubes with multifunctionality, rationally designed and fabricated nanotube arrays with controllable structures are highly desired, but still remain a great challenge. Herein, we report a facile synthesis strategy for core-branched CoSe2/Ni0.85Se nanotube arrays directly on Ni foam by simply selenizing Co-precursor nanowires for hybrid supercapacitors. This structure design could not only ensure the intimate contact of self-branched heterostructures, but also offer sufficient active sites for electrochemical reactions. Further, we propose an electrochemical activation strategy to fully boost the electrochemical performance of CoSe2/Ni0.85Se nanotube arrays. After electrochemical activation, CoSe2/Ni0.85Se nanotube arrays have been changed into porous CoOOH/NiOOH, accounting for the remarkable performance. Contributed to by short ion diffusion paths, large electroactive sites and low contact resistance, the CoSe2/Ni0.85Se electrode after electrochemical activation shows remarkable performance for hybrid supercapacitors.
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