Hydrogen bonding and surface tension properties of aqueous solutions of tetrahydrofuran

Hydrogen bonding and surface tension properties of aqueous solutions of tetrahydrofuran
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四氢呋喃水溶液的氢键和表面张力特性

DOI:
10.1080/00387010.2021.1987271
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发表时间:
2021-10
影响因子:
1.7
通讯作者:
Hongyun Wang
Hongyun Wang
中科院分区:
化学4区
文献类型:
--
作者:
Fang Liu;Pianpian Chang;Yuxuan Zhang;Mingzhe Zhang;Shunli Ouyang;Nannan Wu;Hongyun Wang

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通过定量拉曼光谱实验,研究了四氢呋喃-水混合物在不同摩尔比下分子间缔合程度的变化。氢键随着四氢呋喃的加入而改变。分析了混合物中氢键作用对表面张力的影响。结果表明,四氢呋喃与水之间氢键的增强有助于降低溶液的表面张力。四氢呋喃的摩尔分数与表面张力呈非线性关系。该研究为丰富多元水溶液体系的氢键理论提供了实验依据。
Significant changes observed in the tetrahydrofuran—water mixtures of different molar ratios have been determined the extent of intermolecular association via quantitative Raman experiment. The hydrogen bonding changes with the addition of tetrahydrofuran. The changes of surface tension are analyzed with hydrogen bonding in the mixtures. The result shows that the strengthening of hydrogen bonding between tetrahydrofuran and water contributes to weak the surface tension in the solutions. The correlation between surface tension and mole fractions of tetrahydrofuran is non-linear. This study provides an experimental basis for enriching the hydrogen bonding theory of multivariate aqueous solution systems.
DOI: --
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