Unexpected stereomutation dependence on the chemical structure of helical vinyl glycopolymers.
Unexpected stereomutation dependence on the chemical structure of helical vinyl glycopolymers.
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DOI：
10.1039/c2cc00036a
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发表时间：
2012-04
影响因子：
4.9
通讯作者：
Jiaxi Cui;Jie Zhang;X. Wan
中科院分区：
文献类型：
--
作者：
Jiaxi Cui;Jie Zhang;X. Wan
化学结构上的微小变化对侧链上带有非手性丁氧基端和手性半乳糖氧基端的对三苯基侧链的螺旋乙烯基聚合物的立体结构、稳定性和转位速率都有显着影响。
A small change in chemical structure causes a remarkable influence on the stereostructure stability and mutarotational rate of helical vinyl polymers bearing laterally attached p-terphenyl pendants with an achiral butoxy terminal and a chiral galactosyloxy terminal.