IMPURITY-VACANCY COMPLEXES IN ELECTRON-IRRADIATED SILICON

IMPURITY-VACANCY COMPLEXES IN ELECTRON-IRRADIATED SILICON
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电子辐照硅中的杂质空位复合物

DOI:
10.1103/physrevb.58.1331
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发表时间:
1998
期刊:
影响因子:
3.7
通讯作者:
S. Dannefaer
S. Dannefaer
中科院分区:
物理与天体物理2区
文献类型:
--
作者:
V. Avalos;S. Dannefaer

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A comprehensive study of $\ensuremath{\simeq}2.5--10\ensuremath{-}\mathrm{MeV}$ electron-irradiated Czochralski Si has been conducted using positron lifetime and Doppler broadening spectroscopies. Eight samples, ranging from heavily doped $n$ type to heavily doped $p$ type, were irradiated simultaneously at room temperature to facilitate quantitative comparisons between the samples. The influence from the oxygen impurity was also investigated by comparison with oxygen-free Si. For lightly doped materials (dopant concentration less than $5\ifmmode\times\else\texttimes\fi{}{10}^{16}/{\mathrm{cm}}^{3})$ the irradiation damage is dominated by free, and negatively charged divacancies for the dose employed in this work $(1.2\ifmmode\times\else\texttimes\fi{}{10}^{18}{e}^{\ensuremath{-}}/{\mathrm{cm}}^{2}).$ For the heavily doped materials (dopant concentrations larger than $5\ifmmode\times\else\texttimes\fi{}{10}^{17}/{\mathrm{cm}}^{3})$ vacancy-dopant complexes dominate, some of which involve divacancies, and in these samples very high introduction rates $(1--4{\mathrm{cm}}^{\mathrm{\ensuremath{-}}1})$ are estimated. In heavily B-doped materials evidence is found for thermally activated trapping by boron divacancy complexes. Association of divacancies with P, Sb, and B dopants was found to modify significantly the Doppler $S$ parameter relative to the value for free divacancies.
A comprehensive study of $\ensuremath{\simeq}2.5--10\ensuremath{-}\mathrm{MeV}$ electron-irradiated Czochralski Si has been conducted using positron lifetime and Doppler broadening spectroscopies. Eight samples, ranging from heavily doped $n$ type to heavily doped $p$ type, were irradiated simultaneously at room temperature to facilitate quantitative comparisons between the samples. The influence from the oxygen impurity was also investigated by comparison with oxygen-free Si. For lightly doped materials (dopant concentration less than $5\ifmmode\times\else\texttimes\fi{}{10}^{16}/{\mathrm{cm}}^{3})$ the irradiation damage is dominated by free, and negatively charged divacancies for the dose employed in this work $(1.2\ifmmode\times\else\texttimes\fi{}{10}^{18}{e}^{\ensuremath{-}}/{\mathrm{cm}}^{2}).$ For the heavily doped materials (dopant concentrations larger than $5\ifmmode\times\else\texttimes\fi{}{10}^{17}/{\mathrm{cm}}^{3})$ vacancy-dopant complexes dominate, some of which involve divacancies, and in these samples very high introduction rates $(1--4{\mathrm{cm}}^{\mathrm{\ensuremath{-}}1})$ are estimated. In heavily B-doped materials evidence is found for thermally activated trapping by boron divacancy complexes. Association of divacancies with P, Sb, and B dopants was found to modify significantly the Doppler $S$ parameter relative to the value for free divacancies.