{HB(3,5-Me2pz)3}2Sm(.eta.2-O2): First Example of a Lanthanide Superoxo Complex
{HB(3,5-Me2pz)3}2Sm(.eta.2-O2): First Example of a Lanthanide Superoxo Complex
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DOI：
10.1021/ja00134a037
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发表时间：
1995-07
影响因子：
15
通讯作者：
Xingwang Zhang;G. Loppnow;R. McDonald;J. Takats
中科院分区：
文献类型：
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作者：
Xingwang Zhang;G. Loppnow;R. McDonald;J. Takats
当紫Sm(TpMe2)2(1)在甲苯中的浆料在-78℃的氧气气氛下搅拌时，固体缓慢溶解，约3h后得到深红色的溶液(方程1)，生动地证明了1与O2之间的快速反应。当溶液被加热到
When a slurry of purple Sm (TpMe2) 2 (1) in toluene was stirred at-78 C under an atmosphere of dioxygen, the solid slowly dissolved and after ca. 3 h an intensely colored red solution was obtained (eq1), a vivid demonstration of ready reaction between 1 and O2. As the solution was allowed to warm to