As-Heteropentacenes: An Experimental and Computational Study on a Novel Class of Heteroacenes
As-Heteropentacenes: An Experimental and Computational Study on a Novel Class of Heteroacenes
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As-杂并五苯：一类新型杂并苯的实验和计算研究
DOI：
10.1021/acs.orglett.8b02660
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发表时间：
2018
期刊：
影响因子：
5.2
通讯作者：
Naka Kensuke
中科院分区：
文献类型：
--
作者：
Imoto Hiroaki;Fujii Toshiki;Tanaka Susumu;Yamamoto Shunsuke;Mitsuishi Masaya;Yumura Takashi;Naka Kensuke
首次合成了含砷杂并五苯化合物，并苯并呋喃、苯并噻吩基苯并呋喃和苯并噻吩基苯并噻吩均由砷原子桥联。它们的结构和性能进行了实验和计算研究，使用X-射线晶体学，光学和电子性能，芳香性，电荷载流子迁移率等，目前的研究结果对新的类杂并苯将扩大功能有机化学。
Arsenic-containing heteropentacenes were synthesized for the first time; bibenzofuran, benzothienyl benzofuran, and bibenzothiophene were bridged by arsenic atoms. Their structures and properties were experimentally and computationally studied using X-ray crystallography, optical and electronic properties, aromaticity, charge carrier mobility, etc. The present findings on the novel class of heteroacenes will expand functional organic chemistry.