Heterogeneous Photocatalysts for Light‐Mediated Reversible Deactivation Radical Polymerization
Heterogeneous Photocatalysts for Light‐Mediated Reversible Deactivation Radical Polymerization
复制标题
用于光介导可逆失活自由基聚合的多相光催化剂
DOI：
10.1002/cptc.202300090
复制
发表时间：
2023
期刊：
影响因子：
3.7
通讯作者：
Pester, Christian W.
中科院分区：
文献类型：
--
作者：
Freeburne, Sarah;Hunter, Brock;Bell, Kirsten;Pester, Christian W.
多相光催化结合了光介导化学的优点和促进光催化剂（通常昂贵）重复使用的催化平台的优点。这为更经济、可持续、安全和用户友好的小分子和大分子化合物的化学合成提供了重要的机会。该贡献概述了异质光催化剂设计及其用于介导聚合的最新进展。我们详细概述了四类异质光催化剂：纳米颗粒、共轭和非共轭聚合物网络、金属有机框架（MOF）和功能化固体载体。
Heterogeneous photocatalysis combines the benefits of light‐mediated chemistry with that of a catalytic platform that facilitates re‐use of (often expensive) photocatalysts. This provides significant opportunities towards more economical, sustainable, safe, and user‐friendly chemical syntheses of both small and macromolecular compounds. This contribution outlines recent developments in the design of heterogenous photocatalysts and their use to mediate polymerizations. We outline four classes of heterogeneous photocatalysts in detail: Nanoparticles, conjugated and non‐conjugated polymer networks, metal‐organic frameworks (MOFs), and functionalized solid supports.