Solvent-induced single-crystal to single-crystal transformation of a 2D coordination network to a 3D metal-organic framework greatly enhances porosity and hydrogen uptake.
Solvent-induced single-crystal to single-crystal transformation of a 2D coordination network to a 3D metal-organic framework greatly enhances porosity and hydrogen uptake.
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DOI：
10.1039/c2cc17298d
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发表时间：
2012-02
影响因子：
4.9
通讯作者：
Liang Wen;P. Cheng;Wenbin Lin
中科院分区：
文献类型：
--
作者：
Liang Wen;P. Cheng;Wenbin Lin
在室温下暴露于CH（2）Cl（2）诱导二维配位网络[Zn（2）L（DMF）（4）]·2DMF·4H（2）O通过金属连接点的二聚化向三维金属有机骨架[Zn（2）L（H（2）O）（2）]·xsolv的单晶向单晶转变，导致骨架稳定性、孔隙率和H（2）吸收能力的显著增强。
Exposure to CH(2)Cl(2) at room temperature induces single-crystal to single-crystal transformation of the 2D coordination network [Zn(2)L(DMF)(4)]·2DMF·4H(2)O to the 3D metal-organic framework [Zn(2)L(H(2)O)(2)]·xsolv via dimerization of the metal-connecting points, leading to significant enhancement in framework stability, porosity, and H(2) uptake capacity.