Diisopropylamide and TMP Turbo-Grignard Reagents: A Structural Rationale for their Contrasting Reactivities
Diisopropylamide and TMP Turbo-Grignard Reagents: A Structural Rationale for their Contrasting Reactivities
复制标题
二异丙酰胺和 TMP 涡轮格氏试剂：对比反应性的结构原理
DOI：
10.1002/ange.201000539
复制
发表时间：
2010
影响因子：
--
通讯作者：
Armstrong D
中科院分区：
文献类型：
--
作者：
Armstrong D
通过EXSY和DOSY NMR的结合研究，二异丙基氨基turbo-Grignard试剂“（iPr2N）MgCl⋅LiCl”（见结构；蓝色N，红色O，绿色Mg，黄色Cl，黑色C）在THF溶液中相互动态交换，分离成几个带电的盐种。
A neutral dimeric molecule in crystal form, the diisopropylamido turbo-Grignard reagent "(iPr2N)MgCl⋅LiCl" (see structure; blue N, red O, green Mg, yellow Cl, black C) separates into several charged ate species in dynamic exchange with each other in THF solution as determined by a combination of EXSY and DOSY NMR studies.