Iron-catalyzed benzylic oxidation with aqueous tert-butyl hydroperoxide
Iron-catalyzed benzylic oxidation with aqueous tert-butyl hydroperoxide
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DOI：
10.1002/adsc.200600553
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发表时间：
2007-04-01
影响因子：
5.4
通讯作者：
Bolm, Carsten
中科院分区：
文献类型：
--
作者：
Nakanishi, Masafumi;Bolm, Carsten
少量氯化铁（2摩尔%）在吡啶中以过氧化叔丁基（TBHP）为氧化剂催化苯基氧化。相应的羰基化合物以高收率得到。
A small amount of iron(III) chloride (2 mol%) catalyzes benzylic oxidations with tert-butyl hydroperoxide (TBHP) as oxidant in pyridine. The corresponding carbonyl compounds are obtained in high yields.