Nafion-H catalysed sulfonylation of aromatics with arene/alkenesulfonic acids for the preparation of sulfones

Nafion-H catalysed sulfonylation of aromatics with arene/alkenesulfonic acids for the preparation of sulfones
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DOI:
10.1039/b104603a
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发表时间:
2001-09-07
影响因子:
4.9
通讯作者:
Prakash, GKS
Prakash, GKS
中科院分区:
化学2区
文献类型:
--
作者:
Olah, GA;Mathew, T;Prakash, GKS

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在nafon - h(一种全氟树脂磺酸催化剂)的存在下,芳烃与合适的芳烃或烷磺酸进行Friedel-Crafts型磺化反应,可以很容易地合成对称和不对称的二芳基/芳基烷基砜。
Synthesis of both symmetric and unsymmetric diaryl/aryl alkyl sulfones is easily achieved by Friedel-Crafts type sulfonylation of aromatics with suitable arene- or alkanesulfonic acids in the presence of Nafion-H, a perfluorinated resinsulfonic acid catalyst.