Silane/MoO2Cl2 as an efficient system for the reduction of esters

Silane/MoO2Cl2 as an efficient system for the reduction of esters
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DOI:
10.1016/j.molcata.2006.03.006
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发表时间:
2006-07-01
影响因子:
--
通讯作者:
Romao, Carlos C.
Romao, Carlos C.
中科院分区:
化学2区
文献类型:
--
作者:
Fernandes, Ana C.;Romao, Carlos C.

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报道了第一种使用高氧化态含氧配合物作为催化剂还原酯的方法。事实证明,硅烷/MoO2Cl2 (5 mol%) 系统能够非常有效地将脂肪族和芳香族酯还原为相应的醇,且收率良好。 (c) 2006 Elsevier B.V. 保留所有权利。
The first method for the reduction of esters using a high oxidation state oxo complex as a catalyst is reported. The system silane/MoO2Cl2 (5 mol%) proved to be very efficient for the reduction of aliphatic and aromatic esters to the corresponding alcohols in good yields. (c) 2006 Elsevier B.V. All rights reserved.