Evidence for surface effects in an electron-capture detector.
Evidence for surface effects in an electron-capture detector.
复制标题
电子捕获探测器中表面效应的证据。
DOI：
10.1016/s0021-9673(01)97736-2
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发表时间：
1984
期刊：
影响因子：
--
通讯作者：
Giese,RW
中科院分区：
文献类型：
--
作者：
Nazareth,A;O'Connell,K;Sentissi,A;Giese,RW
我们已经发现，在传统的电子捕获探测器的表面效应是显着减少在实验中，更惰性的版本，这种探测器，这两个由瓦里安。这些表面效应产生了独特的模式，农药，除草剂和衍生的胞嘧啶强的溶质响应。随着溶质浓度的增加，它们也会导致响应因子出现最小值，然后出现更明显的最大值，这一点用线性回归得到了证明。某些推测，以解释这些意见。
We have found surface effects in a conventional electron-capture detector that are signifacantly reduced in an experimental, more inert version of this detector, both by Varian. These surface effects generate unique patterns of solute response for both pesticides—herbicides, and derivatized cytosine strong electrophores. They also cause a minimum followed by a more pronounced maximum in the response factor with increasing solute concentration, demonstrated with lindane. Certain speculations are presented to account for these observations.