Self-assembly of nanoscopic coordination cages of D3h symmetry
Self-assembly of nanoscopic coordination cages of D3h symmetry
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DOI：
10.1073/pnas.012540799
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发表时间：
2002-04-16
影响因子：
11.1
通讯作者：
Stang, PJ
中科院分区：
文献类型：
--
作者：
Kuehl, CJ;Kryschenko, YK;Stang, PJ
A family of nanoscale-sized supramolecular cage compounds with a trigonal prismatic framework was prepared by means of spontaneous self-assembly from the combination of a predesigned molecular "clip" with tritopic pyridyl subunits. As confirmed by x-ray crystallography, the smallest structure of the reported series is approximate to1 x 2 nm and possesses a nitrate anion incarcerated inside its molecular cavity. The largest structure has dimensions of approximate to 1 x 4 nm.
