A General Synthesis of Amines and Hydrazines by Oxidation of Amidocuprates and Zinc-Amidocuprates
A General Synthesis of Amines and Hydrazines by Oxidation of Amidocuprates and Zinc-Amidocuprates
复制标题
氨基铜酸盐和氨基铜酸锌氧化合成胺和肼的通用方法
DOI：
10.1055/s-1997-1218
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发表时间：
1997
期刊：
影响因子：
--
通讯作者：
G. Seconi
中科院分区：
文献类型：
--
作者：
F. Cane;D. Brancaleoni;P. Dembech;A. Ricci;G. Seconi
根据亲电胺化协议，通过氧化分解容易生成的胺基铜酸锂和锌，合成了一系列的胺和肼。通过有机金属簇合物和氧化剂的性质的适当组合，实现了产率的优化。
A wide range of amines and hydrazines were synthesized according to an electrophilic amination protocol by oxidative decomposition of readily generated lithium-and zinc-amidocyanocuprates. Optimization of the yields was achieved by the appropriate combination of the organometallic cluster and the nature of the oxidizing agent.