Heterogeneous Platinum Catalysts for Direct Synthesis of Trimethylamine by N-Methylation of Ammonia and Its Surrogates with CO2/H2
Heterogeneous Platinum Catalysts for Direct Synthesis of Trimethylamine by N-Methylation of Ammonia and Its Surrogates with CO2/H2
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DOI：
10.1246/cl.160875
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发表时间：
2017-01
影响因子：
1.6
通讯作者：
Takashi Toyao;S. H. Siddiki;Keisuke Ishihara;K. Kon;Wataru Onodera;K. Shimizu
中科院分区：
文献类型：
--
作者：
Takashi Toyao;S. H. Siddiki;Keisuke Ishihara;K. Kon;Wataru Onodera;K. Shimizu
通过使用 Pt 和 MoOx 共负载 TiO2 (Pt-MoOx/TiO2)，通过 NH3 或其替代物 (NH4HCO3) 与 CO2 和 H2 的 N-甲基化直接合成三甲胺。在三甲胺合成过程中，Pt-MoOx/TiO2 被发现优于其他负载 Pt 和负载过渡金属的 MoOx/TiO2 催化剂。
Direct synthesis of trimethylamine through N-methylation of NH3 or its surrogate (NH4HCO3) with both CO2 and H2 has been achieved by employing Pt and MoOx coloaded TiO2 (Pt-MoOx/TiO2). Pt-MoOx/TiO2 was found to be superior to other supported Pt and transition-metal-loaded MoOx/TiO2 catalysts for the trimethylamine synthesis process.