A Ni(II)-MOF: reversible guest adsorption and heterogeneous catalytic properties for silylcyanation of aromatic aldehydes.
A Ni(II)-MOF: reversible guest adsorption and heterogeneous catalytic properties for silylcyanation of aromatic aldehydes.
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DOI：
10.1039/c4cc08003c
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发表时间：
2015-01
影响因子：
4.9
通讯作者：
Xiao-Meng Zhang;Chao-Wei Zhao;Jianping Ma;Yang Yu;Qi-kui Liu;Yu‐Bin Dong
中科院分区：
文献类型：
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作者：
Xiao-Meng Zhang;Chao-Wei Zhao;Jianping Ma;Yang Yu;Qi-kui Liu;Yu‐Bin Dong
一个多孔的Ni（II）-MOF，这是由一个新的弯曲的芴桥联配体和NiCl 2在溶剂热条件下构建，可以可逆地吸收有机溶剂分子和碘物种在单晶到单晶（SC-SC）的方式。此外，所获得的I2-Ni（II）-MOF可以是一个高活性的非均相催化剂，以促进无溶剂的芳香醛的硅烷氰化反应在温和的条件下。
A porous Ni(II)-MOF, which was constructed from a new bent fluorene-bridged ligand and NiCl2 under solvothermal conditions, can reversibly uptake organic solvent molecules and iodine species in a single-crystal-to-single-crystal (SC-SC) fashion. Furthermore, the obtained I2⊂Ni(II)-MOF can be a highly active heterogeneous catalyst to promote solvent-free silylcyanation of aromatic aldehydes under mild conditions.